Friday, 24 March 2023

Revealed: the US is averaging one chemical accident every two days

Guardian analysis of data in light of Ohio train derailment shows accidental releases are happening consistently

Mike DeWine, the Ohio governor, recently lamented the toll taken on the residents of East Palestine after the toxic train derailment there, saying “no other community should have to go through this”.

But such accidents are happening with striking regularity. A Guardian analysis of data collected by the Environmental Protection Agency (EPA) and by non-profit groups that track chemical accidents in the US shows that accidental releases – be they through train derailments, truck crashes, pipeline ruptures or industrial plant leaks and spills – are happening consistently across the country.

By one estimate these incidents are occurring, on average, every two days.

“These kinds of hidden disasters happen far too frequently,” Mathy Stanislaus, who served as assistant administrator of the EPA’s office of land and emergency management during the Obama administration, told the Guardian. Stanislaus led programs focused on the cleanup of contaminated hazardous waste sites, chemical plant safety, oil spill prevention and emergency response.

In the first seven weeks of 2023 alone, there were more than 30 incidents recorded by the Coalition to Prevent Chemical Disasters, roughly one every day and a half. Last year the coalition recorded 188, up from 177 in 2021. The group has tallied more than 470 incidents since it started counting in April 2020.

The incidents logged by the coalition range widely in severity but each involves the accidental release of chemicals deemed to pose potential threats to human and environmental health.

In September, for instance, nine people were hospitalized and 300 evacuated in California after a spill of caustic materials at a recycling facility. In October, officials ordered residents to shelter in place after an explosion and fire at a petrochemical plant in Louisiana.

Among multiple incidents in December, a large pipeline ruptured in rural northern Kansas, smothering the surrounding land and waterways in 588,000 gallons of diluted bitumen crude oil. Hundreds of workers are still trying to clean up the pipeline mess, at a cost pegged at around $488m.

The precise number of hazardous chemical incidents is hard to determine because the US has multiple agencies involved in response, but the EPA told the Guardian that over the past 10 years, the agency has “performed an average of 235 emergency response actions per year, including responses to discharges of hazardous chemicals or oil”. The agency said it employs roughly 250 people devoted to the EPA’s emergency response and removal program.

Live in daily fear of an accident’

The coalition has counted 10 rail-related chemical contamination events over the last two and a half years, including the derailment in East Palestine, where dozens of cars on a Norfolk Southern train derailed on 3 February, contaminating the community of 4,700 people with toxic vinyl chloride.

The vast majority of incidents, however, occur at the thousands of facilities around the country where dangerous chemicals are used and stored.

“What happened in East Palestine, this is a regular occurrence for communities living adjacent to chemical plants,” said Stanislaus. “They live in daily fear of an accident.”

In all, roughly 200 million people are at regular risk, with many of them people of color, or otherwise disadvantaged communities, he said.

There are close to 12,000 facilities across the nation that have on site “extremely hazardous chemicals in amounts that could harm people, the environment, or property if accidentally released”, according to a Government Accountability Office (GAO) report issued last year. These facilities include petroleum refineries, chemical manufacturers, cold storage facilities, fertilizer plants and water and wastewater treatment plants, among others.

EPA data shows more than 1,650 accidents at these facilities in a 10-year span between 2004 and 2013, roughly 160 a year. More than 775 were reported from 2014 through 2020. Additionally, after analyzing accidents in a recent five-year period, the EPA said it found accident-response evacuations impacted more than 56,000 people and 47,000 people were ordered to “shelter-in-place.”

Accident rates are particularly high for petroleum and coal manufacturing and chemical manufacturing facilities, according to the EPA. The most accidents logged were in Texas, followed by Louisiana and California.



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Monday, 6 March 2023

For Ann Arbor water managers, ongoing battle to keep toxic chemicals at bay

 





ANN ARBOR – Brian Steglitz and his staff had only recently gotten a handle on the last surprise contaminant to threaten Ann Arbor’s drinking water system when the call came in about another.

A plume of industrial wastewater, thought to be tainted with toxic hexavalent chromium, had entered the Huron River last August after spilling from a chrome-plating facility upstream. It was headed toward Ann Arbor’s intake pipes.

Though the heavy metal is toxic, federal and state drinking water standards say nothing about how much can safely enter public water supplies, and Ann Arbor’s water treatment plant, like most, was not set up to deal with it.

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“We started looking at what our contingency plans are, you know?” said Steglitz, the city’s public services area administrator. “Like, if we're going to treat it, how do we do it? What happens if it gets there and we can't treat it?”

Steglitz and his crew would work nearly around-the-clock in the following days, mixing chemicals to identify a treatment mix that could remove chromium.

In the end, the crisis was averted: Most of the metal spilled from the plant, Tribar Manufacturing, had transformed into a more benign element before it reached the river. But the scare wasted city resources and left water customers on edge for weeks.

And it left Steglitz irritated that he and his staff have to spend so much energy reacting to chemical threats that compromise Ann Arbor’s drinking water.

“It's frustrating,” he said. “But you know, like, this is the world we live in.”

The Clean Water Act, a landmark federal pollution control law passed in 1972, cleaned up American waterways once fouled by industrial waste. But the act was focused largely on making rivers fishable and swimmable — not keeping them free of contaminants that can sully drinking water.

And it was written when the tests used to detect pollution in waterways were more rudimentary, and the public knew less about the perils of some substances that flow out of industrial waste pipes, seep off roads and lawns, or make their way into lakes and streams after being tossed in the trash.

Though testing capabilities and our knowledge of the risks have improved, regulations to protect America’s waterways, and ultimately its drinking water, from a range of troubling contaminants have been slow to follow. The result: a water safety system tilted more toward responding to toxic releases than trying to prevent them in the first place.

That leaves Ann Arbor — and similar communities across the country — to filter out pollution they didn’t cause in order to deliver safe water at the tap.

“The whole thing would be a lot cheaper,” said Bonnifer Ballard, executive director of the Michigan Section of the American Water Works Association, “if we just protected our source of water to begin with.”

The cost to Ann Arbor from the hexchrome scare was mostly in staff time as workers abandoned other duties to respond.

More financially quantifiable is Ann Arbor’s cost to respond to PFAS, another toxic chemical first detected by Ann Arbor in 2014 and later traced up the Huron River to the same chrome plating plant, Tribar. Since the discovery, Ann Arbor has spent $1.5 million upgrading its water system to strip away PFAS, and another $250,000 yearly on maintenance.

And then there’s money to prepare for the possibility of dioxane entering the city’s water supply — another pollutant not subject to drinking water regulations. Tainted groundwater is spreading from a property where the Gelman Sciences company used to manufacture medical filters, and inching toward Ann Arbor’s city-owned drinking water wells.

Communities across the country face similar threats from chemicals that industry discharged freely into waterways for decades before anyone became aware of the risks. ​​

In the case of PFAS alone, a U.S. Government Accountability Office report in September found that one-in-five water systems across six states had unsafe levels of PFOA and PFOS. The chemicals also harm fish and wildlife in rivers, rendering the meat unsafe to eat.

And that’s to say nothing of other so-called “emerging contaminants,” from microplastics to pharmaceuticals, that are widespread and largely unregulated in U.S. waterways, and whose health and environmental impacts aren’t yet well-understood.

As Ann Arbor also prepares for a $100 million overhaul of its water treatment system, it is building a $2.5 million demonstration plant in hopes of being prepared for the next surprise threat. About the size of a modest house, the pilot plant will allow water operators to test new treatments to deal with existing water contamination problems and those that may arise in the future.

It's’ the right thing to do to protect the city’s residents, Steglitz says. But he would prefer that state and federal regulators move faster to identify threats to the city’s sourcewater, and then limit their release into the Huron River.

“Waiting for the EPA is just not going to be the solution any longer, because they’re just too slow,” he said.

Toxicologist Linda Birnbaum blames the nationwide struggle with emerging contaminants on the failings of three landmark federal environmental laws — the Clean Water Act, the Safe Drinking Water Act and the Toxic Substances Control Act — that are supposed to keep pollutants out of our environment.

Birnbaum, who headed the National Institute of Environmental Health Sciences, said EPA regulators working under those laws are too quick to approve chemicals for commercial use without studying the risks, and too slow to prevent releases into waterways when the risks become clear.

When enacted in 1972, the Clean Water Act promised to end pollution of America’s waterways by 1985. A half-century later, conditions have vastly improved in rivers once so fouled by industry, they occasionally caught fire. This was accomplished by requiring industries, public utilities and other so-called “point source” polluters to install technology that pulls certain pollutants from wastewater before they’re released into rivers.

But efforts to add new pollutants to the list haven’t kept pace with our growing understanding of the risks from substances that weren’t on regulators’ radar 50 years ago, including PFAS.

Meanwhile, a separate law, the Toxic Substances Control Act, tasks the EPA with reviewing the risks of new chemicals before they hit the market. Environmentalists have long complained that regulators are too quick to green light new chemicals.

Until recently, the EPA let the vast majority go to market with little vetting to confirm their safety. Reforms in 2016 required deeper reviews of tens of thousands of chemicals already in use, plus the new ones introduced each year. But companies frequently find exemptions, and EPA officials say staffing shortages make it impossible to keep pace as new chemicals are developed.

John Dulmes, executive director of the Michigan Chemistry Council, an industry group, criticized the 2016 reforms, saying they’ve “slowed the approval of new chemicals to a near-halt,” at times blocking innovation that has environmental benefits.

For example, U.S. Representatives Elissa Slotkin and Tim Walberg and Senators Gary Peters and Debbie Stabenow wrote to the EPA in April to complain that a slow-moving review process for carbon nanotubes needed to make battery cells could delay the opening of a new Lansing-area Ultium Cells plant.

Dulmes said those arguing for the regulatory system to take a slower, “precautionary” approach aren’t “appreciating the likely consequences for our economy.”

A third law, the Safe Drinking Water Act, dictates which substances drinking water providers must remove from water before the water can be distributed to customers. Here too, critics say, federal regulators have been slow to react to threats from new contaminants.

The three regulatory systems are not particularly well-aligned, said Birnbaum, who is also former director of the National Toxicology Program.

“When they were first set up in the ‘70s, I'm not sure we were as aware as we are today that everything is interconnected,” Birnbaum said.

PFAS, a class of thousands of persistent chemicals used in everything from nonstick coating to waterproof boots, is a prime example. Many PFAS compounds hit the market without any close study of their health effects. Companies like 3M continued to manufacture two PFAS compounds, PFOA and PFOS, long after internal studies revealed health concerns including cancer.

The EPA was aware of those concerns by the 1990s. Yet decades later, federal regulators still haven’t limited how much PFAS is allowed in rivers, lakes and drinking water, nor forced PFAS-using industries to filter the compounds out of their wastewater. In the interim, the toxic “forever chemicals” have made their way into waterways around the globe, and into the blood of nearly everyone on earth.

Despite numerous requests over more than a week, a spokesperson for the U.S. EPA failed to make someone available to speak with Bridge Michigan and Michigan Radio about the agency’s approach to approving new chemicals and managing the onslaught of water contamination from them.

EPA officials are drafting surface water and drinking water PFAS regulations, but it’s not clear when they’ll take effect.

Beset by PFAS contamination and frustrated by federal inaction, Michigan over the past decade has developed its own limits for a handful of PFAS compounds. But the lack of nationwide regulations leaves residents in many states unprotected, and compromises the shared water of the Great Lakes. Minnesota, Illinois, and Indiana, and Ohio lack enforceable drinking water standards, according to the national environmental health alliance Safer States.

“We have to start trying to look at a lifecycle approach,” Birnbaum said. That means establishing pollution control limits on chemicals as soon as they’re approved for use. Without such precautions, she said, “we seem always to be playing catch-up.”



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Toxic 'forever chemicals' force Mass. towns to face 'true cost of water'



Littleton's new water treatment plant is not, shall we say, a head-turning architectural marvel. It's a large, unadorned brick building resembling a fieldhouse. Or perhaps an overgrown shed.

But when Nick Lawler looks at it, he beams.

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"A thing of beauty!" Lawler, the general manager of the Littleton Electric Light and Water Departments, said. "It's not the outside that matters — it's what's inside."

What's inside is a $16 million, state-of-the-art plant designed to treat Littleton's drinking water for the toxic chemicals known as "PFAS." The so-called "forever chemicals" have contaminated drinking water supplies across Massachusetts, and there's no easy or cheap way to remove them.

For a town with only 10,000 residents, $16 million was a big price tag: the utility's annual water budget is usually around $4 million. And with more regulations expected soon, the price of clean drinking water in the state is about to get a lot higher.

Lawler's colleague, Water and Sewer Superintendent Corey Godfrey, stepped into the cavernous plant to point out four 24-foot-tall steel tanks — "filter vessels" that will remove PFAS from the water. They dwarfed the other tanks in the room.

"They go down into the basement," Godfrey said, peering down a still-unfinished hole. He said each tank will be filled with 20 tons of activated charcoal. "That’s the carbon you need to remove the amount of PFAS we have."







Littleton isn't the only town spending millions to clean up the chemicals. Barnstable has so far invested $27 million to deal with PFAS, for example; and Cambridge recently spent $8.5 million to temporarily switch water supplies while changing its PFAS filters.

But the PFAS costs for Massachusetts communities may just be beginning. The Environmental Protection Agency (EPA) is expected to release its own, potentially stricter, rules in March. These new regulations could cause the price of clean drinking water in the state to soar.

"Substantial investments have been made in Massachusetts to the tune of $100 million-plus already," said Jennifer Pederson, executive director of the Massachusetts Water Works Association, an industry group. "I’m hoping everyone supports clean drinking water, but we know that at times when it comes up for town meeting votes, it's been a challenge to get people to understand that they have to pay that true cost of water."
A drop of water in a swimming pool

In 2020, Massachusetts set a limit on the amount of PFAS in public drinking water. The state limit is one of the strictest in the country: 20 parts per trillion for the sum of six PFAS chemicals. That’s like a drop of water in a swimming pool.

"All the other drinking water standards for all the other chemicals are in the concentration range of parts per billion or parts per million. ...That gives you a sense of really how toxic these chemicals are," said Wendy Heiger-Bernays, a toxicologist at the Boston University School of Public Health.

PFAS chemicals were invented in the early 20th century. Because they have useful properties, companies have used them in thousands of products, from food packaging to waterproof jackets to firefighting foam. Over time the chemicals wash or flake or crumble off these products into landfills, soil, water, air and human bodies.

PFAS molecules don't break down easily, hence the "forever chemical" nickname. And because they are so pervasive, they may as well be called "everywhere chemicals," too. In Massachusetts, they're widespread in ground and surface waters, rivers and even Cape Cod ponds. Studies estimate that 98% of Americans have detectable levels of PFAS in their blood.

Heiger-Bernays, an expert on the toxicology of PFAS, advised the state on their drinking water regulations. She said she was satisfied with the rules: "I mean, as a public health professional, I would like to see the most protective approach taken," she said.

But she said she's also a pragmatist, and she acknowledged that getting PFAS levels down to that drop-in-a-pool level is difficult and expensive.

"The cost of doing this is enormous," she said. "I mean, it's absolutely mind-boggling."



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Friday, 3 March 2023

New theory provides answers to why metals have the structures that they do



A simple new theory that can explain why a metal forms a particular structure has been developed.1 The method allows researchers to understand and predict structures in solid compounds and alloys over a wide range of conditions. ‘This theory is based on our finding that the electrons in many metals occupy so-called quasi-atom orbitals, which are local quantum orbitals centred at the voids between atoms,’ explains Russell Hemley at the University of Illinois Chicago in the US, who led the study together with Maosheng Miao from California State University, Northridge. ‘The chemical interactions between such localised electrons control the metal structures,’ he adds.

‘This new chemical perspective of metals is [an] alternative to the traditional free electron gas model provided by physicists,’ comments Álvaro Lobato, a theoretical chemist at the Complutense University of Madrid in Spain who wasn’t involved in the study. He says that in the new chemical model, the metals behave like inorganic crystals with positive cores and quasi atoms interacting as cations and anions.

‘Determining the metal structures and their pattern across the periodic table is a puzzle that has remained unsolved since the first structure of metals was detected by x-ray diffraction about 100 years ago,’ points out Hemley. He notes that the structures of several classes of metals still can’t be described by the ‘physics’ or band–structure model. ‘Even though we can explain many advanced properties of metals and other compounds, such as superconductivity, we don’t understand why some metals crystallise in the face-centred cubic structure, others take on the hexagonal close-packed structure and some crystallise as body-centred cubic.’

But the structural changes that happen when metals are put under pressure are even more puzzling, adds Hemley. ‘Many metals give up high-symmetry structures and transform to lower symmetry and large voids, so there are many high-pressure structures that aren’t close-packed, which is counter-intuitive.’

‘These structural transformations are caused by an effect that we call sublattice interactions,’ says Miao. He explains that the metal lattice can be split into two sublattices. ‘If the electron localisations of the sublattices match, the intercalation of the sublattices stabilises the structure, but if the electron localisations cause repulsive interactions between the two sublattices, that will destabilise the whole structure,’ he says. ‘Under high enough pressure, all high-symmetry structures become repulsive, so the metal has no choice but to adopt structures with larger voids and lower symmetry.’

To understand different systems, the team carried out precise quantum mechanics calculations that included well-defined electron states and performed simulations of many metals’ structures across the periodic table, including under compression. They carefully examined the electronic states of many metal lattices with varying metals, lattices and sizes and analysed the electron localisation.

José Manuel Recio, a materials scientist at the University of Oviedo in Spain, says that the new theory represents a fundamental advance in the understanding of materials at the atomic level because of its general perspective. ‘Not only for crystalline solids under ambient conditions, but also for its extension to extreme pressure and temperature conditions.’

The researchers were originally looking for a simple chemical explanation for the existence of high-pressure electrides, a surprising phenomenon in which some alkali metals can become transparent insulators under pressure. ‘Investigating this question led us to a simple theory that works for many other elemental metals and compounds under ambient conditions,’ says Hemley. ‘This is an example of how the study of matter under extreme conditions can inform us about chemistry and materials under normal or more familiar conditions.’

Miao points out that the theory has some limitations as metal structures are the result of many factors, including temperature, the nuclear quantum effect and magnetic interactions. ‘None of these are included in the current approach,’ he adds. ‘However, in most of these more complex cases, the local electron chemistry is still the major contribution to structural preferences.’

The new approach, which can be used to predict the behaviours of different types of solids including superhydrides, low-dimensional materials, intermetallics and ionic compounds, could help scientists to find materials with exciting properties. ‘Our conceptual framework and the related theory for compounds can be used to search for and predict new metal superhydrides that might superconduct under high temperatures and lower pressure,’ says Miao.



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Thursday, 2 March 2023

Chemists make alkyl chlorides with less waste










Chemists have figured out how to produce an industrially important reaction in a very economical way. Usually, adding a hydrochloric acid across a double bond involves two steps­—an oxidation and a reduction—and requires a 1:1 ratio of both the oxidant and the reductant. Now Tobias Ritter and coworkers at the Max Planck Institute for Kohlenforschung and RWTH Aachen University devised a method that requires only adding a photocatalyst and visible light to the starting material and hydrochloric acid (Nat. Catal. 2023, DOI:10.1038/s41929-023-00914-7). This new finding represents reactivity that’s the opposite of a well-established mechanism in organic chemistry, and it’s a way to make commodity chemicals with less waste. In college organic chemistry class, students usually learn about the Markovnikov rule: when adding a mineral acid across a carbon-carbon double bond, the compound that comes from the stablest carbocation is the one that will form. Anti-Markovnikov reactions, which have the opposite selectivity, are well known to come out of radical reactions of mineral acids, but these require some sort of stoichiometric initiator. This reaction does not, Ritter says. The researchers used cheap available mineral acids, such as HCl, and added them across simple olefins to form an alkyl chloride, he says. This is not the first time that chemists have made an alkyl chloride from an olefin, Ritter says. “There are a lot of other robust, cheaper methods than what we have here,” he says. But this is the first time anyone has done this reaction with high atom economy, he says. The real target for industrial chemists is taking a cheap feedstock chemical and adding water across a double bond to make primary alcohols, a starting material for a massive amount of industrial chemicals, Ritter says. This new method represents a step toward making those reactions with less waste.

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